Surface catalyzed formation of polychlorinated dibenzo-p-dioxins/dibenzofurans during municipal waste incineration

A series of reactions was carried out on different surfaces using carbon and CuCl₂, and KCl or HCl as a Cl-source. The PCDD/PCDF congener distribution was seen to vary to a great extent but the isomer distribution remained fairly constant. It is concluded that thermodynamic properties are largely responsible for the PCDD/PCDF isomer distribution. With pentachlorobenzene Cl₂ elimination, assisted by oxygen, appears to be the major pathway for PCDD/PCDF formation.     

高炉煤气袋式除尘系统的问题及改进

钢铁生产会产生大量的煤气.袋式除尘是高炉煤气除尘的发展方向.对重钢高炉煤气袋式除尘系统问题的分析研究结果表明:要使钢铁企业煤气除尘系统更高效、低耗、环保的运行,必须采用灵活、可操作性强的煤气温度调节手段,选择适宜的阀门和喷吹控制方式,优化除尘灰的保温模式和卸灰设备的结构等.     

Solubilization of substituted indole compounds by beta-cyclodextrin in water

The solubilization of four pairs of substituted indole compounds (SICs) by β-cyclodextrin (β-CD) in water was investigated. The results show that 1,2,3,4-tetrahydrocarbazole and N-methyl-1,2,3,4-tetrahydrocarbazole form 1:1 inclusion complexes with β-CD, while the other six SICs form 1:2 inclusion complexes, respectively. To each pair of SICs with similar structures, the differences between their solubilization in β-CD/water solutions has been explained by the difference of their contact area within the β-CD cavity, the difference of their molecule polarity, or the presence of hydrogen bond between SIC molecule and β-CD molecule.     

砷形态分析方法研究进展

本文从分离和测定两个方面对砷形态分析方法的发展情况作了评述，引用有关文献７７篇。     

水体溶解性有机物的化学分级表征:原理与方法

综述了水体溶解性有机物(DOM)的化学分级表征法即树脂吸附分级法(RA)的研究与进展,同时基于该方法存在的一些问题结合我国典型水质体系,从树脂的选择、净化、分级的定义、水样过柱流速、水样树脂体积比的确定等方面进行了研究探讨,给出了完整的实验参数和操作方法.     

Analysis of the health risk of exposure to breast milk mercury in infants in Taiwan

The aim of this study was to assess the total concentration and health risk to infants of breast milk mercury in urban mothers and mothers married to fishermen in relation to fish intake in Taiwan. A total of sixty-eight healthy mothers were recruited for the study. The breast milk mercury geometric mean concentration was 2.02 microgl(-1) (n=56, range: 0.24-9.45 microgl(-1)) for the city group and 2.04 microgl(-1) (n=12, range: 0.26-8.62 microgl(-1)) for the fishermen's group. Of the three sources of mercury exposure (i.e., ingestion (breast milk), inhalation (ambient air), and dermal exposure (shower)), breast-feeding was found to be the largest (96.3-99.6% of the total). From a Monte Carlo simulation, in which methyl mercury accounted for about 50% of total mercury, the hazard quotient (exposure estimate/oral minimal risk level or target organ toxicity dose) exceeded 1.0 for 12.9% of urban babies and 18.8% of fishermen's babies (chronic oral minimal risk level and target organ toxicity dose: 3 x 10(-4)mgkg(-1)d(-1)). The calculated mercury exposure was 3.02 x 10(-1) microgkg(-1)d(-1) for a 3.49 kg urban baby boy and 3.06 x 10(-1) microgkg(-1)d(-1) for a 3.44 kg urban baby girl. These results suggest the life style of mothers (eating raw fish and shellfish such as used in "Sashimi" and "Sushi," and vitamin supplementation) may influence the mercury concentration in breast milk.     

Determination of 2,3,7,8-tetrachlorodibenzo-p-dioxin in fresh water fish

Validated sample preparation procedures and high resolution gas chromatography-high resolution mass spectrometry techniques were utilized for the quantitative measurement of 4 to 695 pg/g (ppt) levels of 2,3,7,8-tetrachlorodibenzo-p-dioxin (2378-TCDD) in the edible portions of fish from the state of Michigan. The methodology and the analytical results are presented.     

黄磷废水处理技术

黄磷废水成分复杂，含P4、F^-和CN^-等多种有毒有害物质，污染严重，须经过处理达标后方可排放。目前国内黄磷废水处理通常采用物化法，其又可分为沉淀氧化法和闭路循环法。分别就这2种技术方法的处理过程及优缺点进行了探讨，并对其存在问题的解决提供了思路。     

乳状液膜法迁移及分离铬(Ⅵ)的研究

本文采用以叔胺N7301为流动载体、兰113A为表面活性剂、煤油为膜溶剂、NaOH作内相试剂的乳状液膜体系迁移分离铬(Ⅵ).研究了其迁移机理,确定了适宜制乳、迁移分离及破乳等有关条件,实验表明,不同浓度的含铬(Ⅵ)水样经液膜处理后,其含铬(Ⅵ)量均降至0.5μg·ml~(-1)以下,低于国家排放标准.     

南亚热带土壤温度动态变化特征及其意义

根据定位系统观测资料,阐述了南亚热带山地常绿森林区、丘陵旱作区和平原水稻区多种土壤的温度变化与气温的关系。观测研究结果表明：低山常绿森林区温度的三维空间差异比丘陵区、平原区大,丘陵区又比平原区大;南亚热带林区的气温、地表温、30cm土温比中亚热带的高,比热带的低：南亚热带林区的谷地气温高于针叶林、混交林和阔叶林,谷地地表温低于针叶林而高于混交林和阔叶林,谷地20m土温低于针叶林、混交林而高于阔叶林;在气温一致的丘陵区栽植植物不同,其地表温、土温略有差异;在平原水稻土区,年气温、地表温、20cm土温差异不大,但30cm以下土温渐显差异;不同地貌单元的气温、地表温和土温的年际差异、年平均温度、各月及0～12～24时的温度动态变化各具特征。根据气温与植物生长的关系,拟把气温＞22℃的4～10月称热季、气温＜22℃的1～3月及11～12月称作凉季。可因地制宜,根据气温和土温的变化特征与土壤水分和作物生长的关系,采取措施调节温度,以利于作物生长。